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2021年 †

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原著論文 †

合成班（高分子） 赤木先生、花崎先生、金子先生（←あとでお名前をとり、通し番号にします）

  1. "Electrorheological Effect of Gold Nanoparticles Coated with Fluorescent Mesogenic Groups Dispersed in Nematic Liquid Crystal", K. Kaneko*, K. Yamashita, D. Fujioka, K. Kaneko, K. Fuchigami, T. Hashishin, T. Hanasaki, Crystals, 2021, 11, 192. (doi:10.3390/cryst11020192)

椿先生、今吉先生（←あとでお名前をとり、通し番号にします）

  1. "Enantioselective Preparation of Mechanically Planar Chiral Rotaxanes by Kinetic Resolution Strategy", A. Imayoshi, B. Lakshmi, Y. Ueda, T. Yoshimura, A. Matayoshi, T. Furuta, T. Kawabata*, Nat. Commun., 2021, 12, 404. (DOI:10.1038/s41467-020-20372-0)

今井先生（←あとでお名前をとり、通し番号にします）

  1. "Magnetic Circularly Polarized Luminescence from PtIIOEP and F2‐ppyPtII(acac) under North‐up and South‐up Faraday Geometries", K. Matsudaira, Y. Mimura, J. Hotei, S. Yagi, K.-i. Yamashita, M. Fujiki, Y. Imai*, Chem. Asian J., 2021, 16, 926-930. (doi:10.1002/asia.202100172) (Front Coverに採用)
  2. "Mirror-symmetric magnetic circularly polarized luminescence from CdS/ZnS core-shell quantum dots: Faraday effect in the photoexcited state" Y. Mimura, M. Fujiki, Y. Imai, Chem. Phys. Lett., 2021, 767, 138353. (doi:10.1016/j.cplett.2021.138353) (Editor's Choice, Front Coverに採用)
  3. "Sign inversion of magnetic circularly polarized luminescence in Iridium(III) complexes bearing achiral ligands", K. Matsudaira, A. Izumoto, Y. Mimura, Y. Kondo, S. Suzuki, S. Yagi, M. Fujiki, Y. Imai*, Phys. Chem. Chem. Phys., 2021, 23, 5074-5078. (doi:10.1039/D0CP05775D) (Front Coverに採用)
  4. "Sign dependence of MCPL spectra on type and position of substituent groups of pyrene and phenanthrene derivatives", N. Hara, M.Kitahara, T. Sugimura, H. Toda, M. Shizuma, A. Ito, M. Miyasaka, M. Fujiki, Y.Imai*, Phys.Chem.Chem.Phys., 2021, 23, 8236-8240. (doi:10.1039/d1cp00259g) (Front Insideに採用)
  5. "Synthesis and Chiroptical Properties of Quinoxaline-Fused Polyaza[5]-[7]helicenes with Orange-Color CPL Emissions", T. Otani*, T. Sasayama, M. Horiuchi, S. Okauchi, H. Kawai, H. Kitahara, Y. Imai, T. Shibata*, Helv. Chim. Acta, 2021, 104, e2100016. (doi:10.1002/hlca.202100016)
  6. "Controlling the sign of Excimer-Origin Circularly Polarised Luminescence by Balancing Hydrophilicity/Hydrophobicity in Bipyrenyl Arginine Peptides", Y. Mimura, Y. Motomura, M. Kitamatsu, Y. Imai*, 'Asian J. Org. Chem.', 2021, 10, 149-153. (doi:10.1002/ajoc.202000549) (Front Insideに採用)
  7. "Sign inversion in magnetic circularly polarised luminescence of fused aromatics with 1.6 T N-up/S-up Faraday geometry", H. Toda, N. Hara, M. Fujiki, Y. Imai*, RSC Adv., 2021, 11, 1581-1585.

八木先生

  1. "Synthesis of novel π-extended D–A–D-type dipyrido[3,2-a:2′,3′-c]phenazine derivatives and their photosensitized singlet oxygen generation", Y. Hayashi, A. Morimoto, T. Maeda, T. Enoki, Y. Ooyama, Y. Matsui,H. Ikeda, S. Yagi*, New J. Chem., 2021, 45, 2264-2275. (doi:10.1039/D0NJ05526C)
  2. "NIR fluorescence of A–D–A type functional dyes modulated by terminal Lewis basic groups" A. Morimoto, Y. Hayashi, T. Maeda, S. Yagi*, Dyes Pigm., 2021, 184, 108768 (7 pages). (doi:10.1016/j.dyepig.2020.108768 )

長谷川

  1. "Small Figure‐Eight Luminophores: Double‐Twisted Tethered Cyclic Binaphthyls Boost Circularly Polarized Luminescence", Y. Nojima, M. Hasegawa*, N. Hara, Y. Imai, Y. Mazaki, Chem. Eur. J., 2021, 27, 5923-5929. (doi:10.1002/chem.202005320) (Front Cover, Hot Paperに採用)
  2. "Circularly Polarized Luminescence of A Stereogenic Curved Paraphenylene Anchoring A Chiral Binaphthyl in Solution and Solid State" K. Sato, M. Hasegawa*, Y. Nojima, N. Hara, T. Nishiuchi, Y. Imai, Y. Mazaki, Chem. Eur. J., 2021, 27, 1323-1329. (doi:10.1002/chem.202004283) (Front Cover, Hot Paperに採用)
  3. "Reduction of Ethynylenes to Vinylenes in Macrocyclic π-Extended Thiophene Skeleton under Mc Murry Coupling Conditions" K. Shirahata, M. Takashika, K. Hirabayashi, "M. Hasegawa*, H. Otani*, K. Yamamoto, Y. Ie, T. Shimizu, S. Aoyagi, M. Iyoda*, J. Org. Chem., 2021, 86, 302–309. (doi:10.1021/acs.joc.0c02080)
  4. "Dinuclear Triple‐Stranded Helicates Composed of Tetradentate Ligands with Aluminum(III) Chromophores: Optical Resolution and Multi‐color Circularly Polarized Luminescence Properties" T. Ono*, K. Ishihama, A. Taema, T. Harada, K. Furusho, M. Hasegawa, Y. Nojima, M. Abe, Y. Hisaeda*, Angew. Chem. Int. Ed., 2021, 6, 2614-2618. (doi:10.1002/anie.202011450).
  5. "Dinuclear Triple-stranded Helicates Comprising Al(III), Ga(III), or In(III) and a Hydrazine-linked Bisiminopyrrolyl Ligand: Synthesis, Structure, Optical Resolution, and Chiroptical Properties", K. Ishihama, T. Ono*, T. Okawara, T. Harada, K. Frusho, M. Hasegawa, Y. Nojima, T. Koida, M. Abe, Y. Hisaeda*, Bull. Chem. Soc. Jpn., 2021, 94, 573-578. (DOI:10.1246/bcsj.20200327)

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2020年 †

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原著論文 †

合成班（高分子）

  1. "Chiral Reaction Field with Thermally Invertible Helical Sense that Controls the Helicities of Conjugated Polymers", K. Akagi*, T. Yamashita, K. Horie, M. Goh, M. Yamamoto, Adv. Mater., 2020, 32, 1906665. (doi:10.1002/adma.201906665) (Frontspecieに採用)
  2. "Photoinvertible Chiral Liquid Crystal that Affords Helicity‐Controlled Aromatic Conjugated Polymers", S. Yoshida, S. Morikawa, K. Ueda, M. Hidaka, K. Kaneko, K. Kaneko, T. Hanasaki, K. Akagi*, Adv. Opt. Mater., 2020, 8, 2000936. (doi:10.1002/adom.202000936)(Inside Front Coverに採用)
  3. "Freedericksz transition in a dual-frequency nematic liquid crystal", Y. Takikawa, K. Kaneko, S. Odani, H. Orihara, M. Iwata, Jpn. J. Appl. Phys, 2020, 59, 041006. (doi:10.35848/1347-4065/ab80e1:)
  4. 「Ni-Co合金ナノ粒子を含むポリイミド樹脂膜の液相還元法による合成」, 藤岡大毅, 金子光佑, 山本悠策, 片山真祥, 稲田康宏, 小島一男, 花﨑知則，材料の科学と工学, 57, 136-140.

合成班（低分子）

椿先生、今吉先生（←あとでお名前をとり、通し番号にします）

  1. "Total Syntheses of FR-901235, Auxarthrones A–D, and Lamellicolic Anhydride", K. Kiyotaki, T. Kayukawa, A. Imayoshi, K. Tsubaki*, Org. Lett. 2020, 22, 9220–9224. (doi:10.1021/acs.orglett.0c03401)
  2. "Nucleophilic addition reactions of benzoxanthone derivatives with collapse of aromaticity", H. Sasaki, T. Hosoya*, N. Egami, H. Ishimura, A. Katori, H. Miyafuji, K. Kuramochi, A. Imayoshi, K. Tsubaki, Tetrahedron Lett., 2020, 76, 131472. (doi:10.1016/j.tet.2020.131472)
  3. "Nitrile oxide cycloaddition reactions of alkenes or alkynes and nitroalkanes substituted with O-alkyloxime groups convertible to various functional groups", N. Umemoto, A. Imayoshi, K. Tsubaki*, Tetrahedron Lett., 2020, 76, 152213. (doi:10.1016/j.tetlet.2020.152213)
  4. "Dimerizations of 2-bromo-3-methyl-1,4-naphthoquinone and 2-methyl-1,4-naphthoquinone in tetra-n-butylammonium bromide" M. Onukia, M. Ota, S. Otokozawa, S. Kamo, S. Tomoshige, K. Tsubaki, K. Kuramochi*, Tetrahedron, 2020, 76, 130899. (doi: 10.1016/j.tet.2019.130899)
  5. "Synthesis and structural revision of an indanone isolated from Triphyophyllum peltatum" Y. Ishii, M. Ota, S. Kamo, S. Tomoshige, K. Tsubaki, K. Kuramochi*, Tetrahedron Lett., 61, 151494 (doi:10.1016/j.tetlet.2019.151494)
  6. "Synthesis and Optical Properties of L-Shaped Dinaphthofluoresceins with two Peripheral Hydroxy Groups", Heterocycles, H. Yamashita, C. Minari, E. Azuma, K. Kuramochi, A. Imayoshi, K. Tsubaki*, 2020, 101, 536–547.(doi: 10.3987/COM-19-S(F)44)
  7. "Nucleophilic Addition Reaction with Dearomatization of Naphthalene Ring", H. Sasaki, K. Kiyotaki, A. Imayoshi, K. Tsubaki*, Chem. Pharm. Bull., 2020, 68, 384–391. (doi:10.1248/cpb.c19-01117)
  8. "Sign control of circularly polarized luminescence by substituent domino effect in binaphthyl-Eu(III) organometallic luminophores", D.Kaji, M. Kitayama, N. Hara, K. Yoshida, S. Wakabayashi, M. Shizuma, K. Tsubaki*, Y. Imai*, J. Photoch, Photobio A, 2020, 397, 11490. (10.1016/j.jphotochem.2020.112490)

杉浦先生（←あとでお名前をとり、通し番号にします）

  1. "Functionalization of Bipyrenol: Potential Precursors for Advanced Chiral Molecules", U. A. Liza, K.-i. Sigiura*, Synthesis, 2020, 52, 3452–3460. (doi:10.1055/s-0040-1707341)
  2. "[2.2]Paracyclophane-Based Chiral Platforms for Circularly Polarized Luminescence Fluorophores and Their Chiroptical Properties: Past and Future", K.-i. Sugiura*, Front. Chem., 2020, 8, 700.(doi:10.3389/fchem.2020.00700)
  3. "Synthesis of Porphyrinquinone and Doubly‐Fused Diporphyrin Quinone Through Oxidation of Diarylporphyrins Using a Hypervalent Iodine Compound", K.-i. Yamashita*, D. Hirano, K. Fujimaki, K.‐i. Sugiura*, Chem. Asian J., 2020, 15, 3037–3043. (doi:10.1002/asia.202000781)
  4. "Metal complexes of 5,15-porphyrinquinones: Systematic study of crystal structure, electronic structure, and Lewis acidity ", K.-i. Yamashita*, D. Hirano, K.-i. Sugiura*, European Journal of Inorganic Chemistry, ''2020', 36, 3507-3516.(doi:10.1002/ejic.202000527)
  5. "Crystal Structure Refinement of 1,4,5,8-Tetrabromonaphthalene: A Twisted Chiral Naphthalene Induced by Steric Repulsion", M. A. Hossain, K. Hirabayashi, T. Nishinaga, T. Shimizu, K.-i. Sugiura*, X-ray Structure Analysis Online, 2020, 36, 35–37. (doi:10.2116/xraystruct.36.35)
  6. "Crystal Structure of 3-(3-Methyl-1H-indole-1-yl)phthalonitrile", S. Ayari, K. Hirabayashi, T. Shimizu, B. Jamoussi, M. F. Saglam, D. Atilla, K.-i. Sigoira, X-ray Structure Analysis Online, 2020, 36, 11–13.(doi:10.2116/xraystruct.36.11)
  7. "Crystal Structure Refinement of 1,4,5,8-Tetrabromonaphthalene: A Twisted Chiral Naphthalene Induced by Steric Repulsion", M. A. Hossain, K. Hirabayashi, T. Nishinaga, T. Shimizu, K.-i. Sugiura*, X-ray Structure Analysis Online, 2020, 36, 35–37. (doi:10.2116/xraystruct.36.35)
  8. "Crystal Structure of 3-(3-Methyl-1H-indole-1-yl)phthalonitrile", S. Ayari, K. Hirabayashi, T. Shimizu, B. Jamoussi, M. F. Saglam, D. Atilla, K.-i. Sugiura*, X-ray Structure Analysis Online, 2020, 36, 11–13.(doi:10.2116/xraystruct.36.11)
  9. "Efficient Synthesis of Arylenedioxy-​Bridged Porphyrin Dimers through Catalyst-​Free Nucleophilic Aromatic Substitution", K.-i. Yamashita*, N. Kuramochi, H. P. Q. Van, K. Furutani, T. K.-i. Sugiura*, Chem Plus Chem, 2020, 85, 217–226. (doi:10.1002/cplu.201900670)

今井先生-------------------------------------------------------------------------------------------------------------

  1. “Development of Circularly Polarized Luminescence (CPL) Peptides Containing Pyrenylalanines and 2-Aminoisobutyric Acid  Y. Mimura, Y. Motomura, M. Kitamatsu*, Y. Imai*, Processes, 2020, 8, 1550. (doi:10.3390/pr8121550)
  2. "Sign control of circularly polarized luminescence by substituent domino effect in binaphthyl-Eu(III) organometallic luminophores", D.Kaji, M. Kitayama, N. Hara, K. Yoshida, S. Wakabayashi, M. Shizuma, K. Tsubaki, Y. Imai, J. Photoch, Photobio A, 2020, 397, 11490. (doi:10.1016/j.jphotochem.2020.112490)
  3. "Generation of Circularly Polarized Luminescence by Symmetry Breaking", Y. Imai*, Symmetry, 2020, 12, 1786. (doi:110.3390/sym12111786)
  4. "Control of Axial Chirality by Planar Chirality Based on Optically Active [2.2]Paracyclophane", G. Namba, Y. Mimura, Y. Imai*, R. Inoue, Y. Morisaki*, Chem. Eur. J., 2020, 26, 14871-14877.(doi:10.1002/chem.202003188)
  5. "Sign inversion of excimer circularly polarized luminescence in water-soluble bipyrenyl oligopeptides through an odd-even effect", Y. Mimura, Y. Motomura, M. Kitamatsu, Y. Imai*, Tetrahedron Lett., 2020, 61, 152238. (doi:10.1016/j.tetlet.2020.152238)
  6. "Multiple Fused Anthracenes as Helical Polycyclic Aromatic Hydrocarbon Motif for Chiroptical Performance Enhancement", K. Fujise, E. Tsurumaki, G. Fukuhara, N. Hara, Y. Imai, S. Toyota*, Chem. Aisan. J., 2020, 15, 2456-2461. (doi:10.1002/asia.202000394)
  7. "Excimer-origin CPL vs. monomer-origin magnetic CPL in photo-excited chiral binaphthyl-ester-pyrenes: critical role of ester direction", H. Okada, N. Hara, D. Kaji, M. Shizuma, M. Fujuiki, Y. Imai*, Phys. Chem. Chem. Phys., 2020, 22, 13862-13866. (doi:10.1039/D0CP02215B)(Back Coverに採用)
  8. "Mirror-image magnetic circularly polarized luminescence (MCPL) from optically inactive Eu-III and Tb(III)tris(beta-diketonate)", H. Yoshikawa, G. Nakajima, Y. Mimura, T. Kimoto, Y. Kondo, S. Suzuki, M. Fujiki*, Y. Imai*, Dalton Trans., 2020, 49, 9588-9594. (doi:10.1039/D0DT01464H)(Back Coverに採用)
  9. "Smart Fluorescence Materials that Are Controllable by Hydrostatic Pressure: Peptide-Pyrene Conjugates", H. Mizuno, M. Kitamatsu, Y. Imai*, G. Fukuhara*, Chem Photo Chem, 2020, 4, 502-507. (doi:10.1002/cptc.202000036) (Front Coverに採用)
  10. "Non-classically Controlled Sign in a 1.6 Tesla Magnetic Circularly Polarized Luminescence of Three Pyrenes in a Chloroform and a PMMA Film", D. Kaji, H. Okada, N. Hara, Y. Kondo, S. Suzuki, M. Miyasaka, M. Fujiki, Y. Imai* Chem. Lett., 2020, 49, 674-676. (doi:10.1246/cl.200136)
  11. "Inter- and intramolecular excimer circularly polarised luminescence of planar chiral paracyclophane-pyrene luminophores"  N. Hara, M. Shizuma, T. Harada, Y. Imai*, RSC ADVANCES, 2020, 10, 11335-11338. (doi:10.1039/D0RA01552K)
  12. "Catalytic Enantioselective Synthesis of Axially Chiral Polycyclic Aromatic Hydrocarbons (PAHs) via Regioselective C-C Bond Activation of Biphenylenes", H. Takano, N. Shiozawa, Y. Imai, K. S. Kanyiva, T. Shibata*, J. Am. Chem. Soc., 2020, 142, 4714-4722. (doi:10.1021/jacs.9b12205)(Front Coverに採用)
  13. "Synthesis and circularly polarized luminescence properties of BINOL-derived bisbenzofuro[2,3-b:3 ',2 '-e]pyridines (BBZFPys)", R. Takishima, Y. Nishii, T. Hinoue, Y. Imai*, M. Miura, Beilstein J. Org. Chem., 2020, 16, 325-336. (doi:10.3762/bjoc.16.32)
  14. "Synthesis and stereochemistry of helical polyurethanes based on 2,2 '-dihydroxy-1,1 '-binaphthyl and diisocyanatobenzenes", H. Dai, Y. Shichibu, Y. Imai, N. Hara, K. Konishi, Y. Wang, Z. Song, T. Nakano* Poly. Chem., 2020, 11, 1134-1144. (doi:10.1039/C9PY01348B)
  15. "Non-classical Control of Circularly Polarized Luminescence based on Precise Placement of Luminescent Units", Y. Imai*, J. Synth. Org. Chem., 2020, 78, 148-157. (doi:10.5059/yukigoseikyokaishi.78.148)
  16. "Circularly polarised luminescence (CPL) control of oligopeptide-Eu(III) hybridized luminophores by interaction with peptide side chains", Y. Mimura, T. Sato, Y. Motomura, H. Yoshikawa, M. Shizuma, M. Kitamatsu, Y. Imai*, RSC Adv., 2020, 10, 2575-2580. (doi:10.1039/C9RA09708B)

八木先生

  1. "Hydrogen bond-rigidified planar squaraine dye and its electronic and organic semiconductor properties", T. Maeda, A. Liess, A. Kudzus, A.-M. Krause, M. Stolte, H. Amitani, S. Yagi,H.Fujiwara, F. Würthner, Chem. Commun., 2020, 56, 9890-9893. (doi:10.1039/D0CC04306K)
  2. "Fluorescent 2-phenyl-2H-benzotriazole dyes with intramolecular N–H···N hydrogen bonding: Synthesis and modulation of fluorescence properties by proton-donating substituents", T. Uesaka, T. Ishitani, R. Sawada, T. Maeda, S. Yagi, Dyes Pigm., 2020, 183, 108672. (doi:10.1016/j.dyepig.2020.108672)
  3. "Room-Temperature Phosphorescence-active Boronate Particles: Characterization and Ratiometric Afterglow-sensing Behavior by Surface Grafting of Rhodamine B" M. Hoshi, R. Nishiyabu, Y. Hayashi, S. Yagi, Y. Kubo, Chem. Asian J., 2020, 15, 787-795. (doi:10.1002/asia.201901740).
  4. "5-アミノ-2-(2-ヒドロキシフェニル)-2H-ベンゾトリアゾール誘導体の合成と蛍光特性", 上坂敏之, 八木繁幸, 前田壮志, 色材協会誌, 93, 194-201. (doi:10.4011/shikizai.93.194)

長谷川（←あとでお名前をとり、通し番号にします）

  1. "Selenacalix[4]selenophene: Synthesis, Structure, and Gel Formation of Cyclic Selenoether of Selenophene" M. Hasegawa*, S. Haga, T. Nishinaga, Y. Mazaki, Org. Lett., 2020, 22, 3755–3758. (doi:10.1021/acs.orglett.0c00839)
  2. "Self-assembly of Radially π-Extended Tetrathiafulvalene Tetramers for Visible and Near Infrared Electrochromic Nanofiber "M. Hasegawa*, M. Iyoda, Bull. Chem. Soc. Jpn., 2020, 93, 154-162. (doi:10.1246/bcsj.20190283)
  3. "Dancing with Sulfur: Facile Preparation of Thiacalix[n]thiophene Derivatives" M. Hasegawa*, J. Org Synth. Chem. , 2020, 78, 1066-1075. (doi:10.5059/yukigoseikyokaishi.78.1066)
  4. "Reversible Color and Shape Changes of Nanostructured Fibers of a Macrocyclic π-Extended Thiophene Hexamer Promoted by Adsorption and Desorption of Organic Vapor" M. Iyoda*, M. Takashika, M. Hasegawa, H. Otani, S. Mizuno, K. Miwa, W. Kariya, T. Fujiwara, H. Shimizu, S. Aoyagi, J. Am. Chem. Soc., 2020, 142, 13662-13666. (doi:10.1021/jacs.0c05340)

長田先生（←あとでお名前をとり、通し番号にします）

  1. "A Large Starphene Comprising Pentacene Branches", J. Holec, B. Cogliati, J. Lawrence, A. Berdonces‐Layunta, P. Herrero, Y. Nagata, M. Banasiewicz, B. Kozankiewicz, M.Corso, D. G. de Oteyza, A. Jancarik*, A.Gourdon*, Angw. Chem. Int. Ed., 60, 7752. (doi:10.1002/anie.202016163)
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著作 †

  1. "Liquid Crystalline Conjugated Polymers with Optoelectronic Functions" K. Akagi, Polymers and Polymeric Composites: A References Series, Springer Nature, 2020, 1-21. (ISBN 978-3-642-37179-0)
  2. ""ポリアセチレンの発見", 1章 高分子 歴史と展望" 赤木和夫, 基礎高分子科学 第2版, 東京化学同人, 2020, 22 (ISBN 9784807909629)
  3. ""階層制御ポリマー", 第４編 (薄膜技術の応用と展望), 第７章 (有機・バイオデバイス), 第2節(π共役高分子薄膜)" 赤木和夫, 2020版薄膜作製応用ハンドブック—, エヌ・ティー・エス, 2020, 1397-1401 (ISBN 978-4-86043-631-5 C3058)
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受賞 †

  1. 高分子科学功績賞, 赤木和夫, (高分子学会), 2020
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新聞報道 †

  1. 「電気通すゲル、医療に応用へ」（長谷川真士）日経産業新聞、2020. 6.4.
  2. 「オリゴフェニレンをねじって輪に。〜円偏光色素〜」（長谷川真士、今井喜胤）科学新聞、2021. 1.8.
  3. 「北里大など、円偏光発光色素を開発、オリゴフェニレンをらせん状に、3Dディスプレイなど応用」（長谷川真士、今井喜胤）化学工業日報、2021. 1.21.
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